On a serving dish, place 1 slice of cake. Spread with 3/4 cup of the buttercream, sprinkle with 1/4 cup of the peanuts and top with 1 disc of peanut butter meltaway. Layer another cake slice and spread with 3/4 cup of the buttercream. Sprinkle with 1/4 cup of the peanuts, 1/2 cup of the caramel popcorn and drizzle with half of the caramel sauce. Repeat the sequence, finishing with the remaining popcorn and caramel sauce (see note).